Aqueous Based Systems
The alternative to Solvents is aqueous based systems, which use water or
emulsions as a cleaning media. Emulsions are relatively simpler to handle, wash
and recycle. But there are issues that are faced during the disposal of the emulsion
waste when the media is to be cleaned.
All emulsions are categorised as water in oil or oil in water
types.
The emulsions are made of emulsifiers which have hydrophobic and
hydrophilic ends. When they are brought in contact with water, the hydrophobic
end attaches itself to water molecule and the hydrophilic end is free and can
easily attach itself to any oil, grease or similar contaminant. This helps in
removal of the contaminant from the media or the substrate.
Emulsions are made by mixing water and the emulsifier under immense
shear and pressure to create a colloidal solution that has a dispersion of
emulsifiers in water. Emulsifiers have the same property as any hydrocarbon
making it an ideal compound to be used in the cleaning. The emulsions are
also made of stabilisers, buffers and other chelating agents.
There are many advantages of using Emulsions. Temperature of washing can
be increased and it can also be operated in an open system. It’s also
compatible with most metals, non-metals, plastics and alloys. Most emulsions
are stable over a wide range of ph, temperatures and can accommodate additives
needed in the washing process.
However emulsions need a process of rinsing and subsequent drying. The
rinsing is compulsory as we need to remove the detergents and soap
remains from the component. This process is not required when dealing with a
solvent based system.
A typical aqueous cleaner is 3 stage:
1) Washing
2) Rinsing
3) Drying.
Most aqueous cleaning agents are made of various compounds to
accommodate different processes. They can incorporate Chelating agents,
sequestering agents, anti-rust compounds, anticoagulants, buffers, stabilizers
and other such compounds. These Chemistries are detailed in a different book.
In summation it can be said that
most metals clean and dry faster in solvent based systems, but we need to study
the economics of using the solvent must be studied in detail. Aqueous
technologies are safer, healthier and less expensive too.
Both Methods have disposal issues. There is a change in the mind-set
of existing users who are moving towards thee aqueous based solutions. Class 1
level of washing needs be augmented with a newer generation of chemicals.
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